Documents and Settings is a system folder you may not move at all. As well as the Windows folder and the Program Files. What you can do is create a virtual disk with both disks. The tool is somewhere in Administration tools in Programs > Accessories.
I'll edit back this post if I remember where it is.
quote:
Originally posted by BluexDreams
P.s : I use Win XP,and a P2P Program that seems to suck space every few mins.
Well, set up the program so that it stores the files in E: and move the downloaded files there (no the folder, but the files only).
Anyway, with that tool I mention above you can virtually merge disks into one with XP.