Shoutbox

It may or may not be possible

https://secure.eu.playstation.com/psn/mypsn/friends/

Anyone on the PSN can sign into that link and see the current status of their friends, along with what game they're currently playing and any status message.

I don't know about getting the information out of that website and into a script.....but in theory it could be possible?

Oh and they certainly do offer games for download