RE: On line alert
When you're talking to someone, then set a Personalized Status (you're supposed to have Messenger Plus! since you've posted this thread on Messenger Plus! Live Extension forum) and set your status Busy, and set an auto-reply like "I'm already chatting with another one" and filter contacts by selecting all your contacts except the contact you're currently chatting with. (Invert Selection button will help you for doing this) They will only be notified when they write to you. But you can simply state that in your personal message when you don't want to be disturbed.
Still, a script may do much more thing about this subject.
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