yeah it is possible. just go to this website
http://carl.kenner.googlepages.com/glovepie
and download the program. it comes with a few scripts to control itunes, winamp, media player and that, so you dont have to create your own. I use it a lot, as i have rechargeable batteries for my wiimote. if i didnt have those batteries i wouldnt bother as the bluetooth suchs the batteries dry pretty quickly